Electron Configuration Practice with Answer Key

Electron Configuration Practice: The Only Drill You Need

You need to write electron configurations. You need to verify if you're right. This guide gives you both — 40 practice problems with a complete answer key.

No fluff. No inspirational quotes. Just electrons filling orbitals the way they actually do.

What You Actually Need to Know First

Before you start the problems, make sure these rules are locked in your brain:

The Orbital Filling Order (Memorize This)

Most students draw this as a diagonal diagram. Here's the sequence:

1s → 2s → 2p → 3s → 3p → 4s → 3d → 4p → 5s → 4d → 5p → 6s → 4f → 5d → 6p → 7s → 5f → 6d → 7p

Or easier — fill this pattern diagonally:

1s
2s 2p
3s 3p 4s 3d
4p 5s 4d 5p 6s 4f
5d 6p 7s 5f 6d 7p

Electron Capacity Per Subshell

Practice Problems

Level 1: Basic Configurations (Problems 1–10)

Write the full electron configuration for each element:

  1. Hydrogen (H)
  2. Helium (He)
  3. Lithium (Li)
  4. Carbon (C)
  5. Nitrogen (N)
  6. Oxygen (O)
  7. Neon (Ne)
  8. Sodium (Na)
  9. Chlorine (Cl)
  10. Argon (Ar)

Level 2: Transition Metals and Beyond (Problems 11–25)

  1. Potassium (K)
  2. Calcium (Ca)
  3. Iron (Fe)
  4. Copper (Cu)
  5. Zinc (Zn)
  6. Bromine (Br)
  7. Krypton (Kr)
  8. Silver (Ag)
  9. Gold (Au)
  10. Lead (Pb)
  11. Mercury (Hg)
  12. Platinum (Pt)
  13. Nickel (Ni)
  14. Manganese (Mn)
  15. Chromium (Cr)

Level 3: Ions and Exceptions (Problems 26–40)

  1. Fe²⁺ (Iron ion with 2+ charge)
  2. Fe³⁺ (Iron ion with 3+ charge)
  3. Cu⁺ (Copper ion with 1+ charge)
  4. Cu²⁺ (Copper ion with 2+ charge)
  5. O²⁻ (Oxide ion)
  6. Na⁺ (Sodium ion)
  7. Cl⁻ (Chloride ion)
  8. S²⁻ (Sulfide ion)
  9. Ti²⁺ (Titanium ion)
  10. Ti⁴⁺ (Titanium ion)
  11. Co²⁺ (Cobalt ion)
  12. Co³⁺ (Cobalt ion)
  13. Zn²⁺ (Zinc ion)
  14. Sn²⁺ (Tin ion)
  15. Sn⁴⁺ (Tin ion)

Answer Key

Level 1 Answers

ElementConfiguration
1. H1s¹
2. He1s²
3. Li1s² 2s¹
4. C1s² 2s² 2p²
5. N1s² 2s² 2p³
6. O1s² 2s² 2p⁴
7. Ne1s² 2s² 2p⁶
8. Na1s² 2s² 2p⁶ 3s¹
9. Cl1s² 2s² 2p⁶ 3s² 3p⁵
10. Ar1s² 2s² 2p⁶ 3s² 3p⁶

Level 2 Answers

ElementConfiguration
11. K1s² 2s² 2p⁶ 3s² 3p⁶ 4s¹
12. Ca1s² 2s² 2p⁶ 3s² 3p⁶ 4s²
13. Fe1s² 2s² 2p⁶ 3s² 3p⁶ 4s² 3d⁶
14. Cu1s² 2s² 2p⁶ 3s² 3p⁶ 4s¹ 3d¹⁰
15. Zn1s² 2s² 2p⁶ 3s² 3p⁶ 4s² 3d¹⁰
16. Br1s² 2s² 2p⁶ 3s² 3p⁶ 4s² 3d¹⁰ 4p⁵
17. Kr1s² 2s² 2p⁶ 3s² 3p⁶ 4s² 3d¹⁰ 4p⁶
18. Ag[Kr] 5s¹ 4d¹⁰
19. Au[Xe] 6s¹ 4f¹⁴ 5d¹⁰
20. Pb[Xe] 6s² 4f¹⁴ 5d¹⁰ 6p²
21. Hg[Xe] 6s² 4f¹⁴ 5d¹⁰
22. Pt[Xe] 6s¹ 4f¹⁴ 5d⁹
23. Ni1s² 2s² 2p⁶ 3s² 3p⁶ 4s² 3d⁸
24. Mn1s² 2s² 2p⁶ 3s² 3p⁶ 4s² 3d⁵
25. Cr1s² 2s² 2p⁶ 3s² 3p⁶ 4s¹ 3d⁵

Level 3 Answers (Ions and Exceptions)

IonConfigurationNotes
26. Fe²⁺[Ar] 3d⁶Lost two 4s electrons
27. Fe³⁺[Ar] 3d⁵Lost two 4s + one 3d
28. Cu⁺[Ar] 3d¹⁰4s electron lost
29. Cu²⁺[Ar] 3d⁹4s + one 3d lost
30. O²⁻1s² 2s² 2p⁶Same as Ne
31. Na⁺1s² 2s² 2p⁶Same as Ne
32. Cl⁻1s² 2s² 2p⁶ 3s² 3p⁶Same as Ar
33. S²⁻[Ar]Same as Ar
34. Ti²⁺[Ar] 3d²Lost both 4s electrons
35. Ti⁴⁺[Ar]Lost 4s and 3d²
36. Co²⁺[Ar] 3d⁷Lost two 4s electrons
37. Co³⁺[Ar] 3d⁶Lost 4s² + one 3d
38. Zn²⁺[Ar] 3d¹⁰Lost both 4s electrons
39. Sn²⁺[Kr] 5s² 4d¹⁰ 5p² → [Kr] 4d¹⁰ 5p²Lost both 5s electrons
40. Sn⁴⁺[Kr] 4d¹⁰Lost 5s² and 5p²

Where Students Actually Screw Up

1. Forgetting the 4s Fills Before 3d

Calcium is 4s², not 3d². The 3d orbitals don't start filling until after you've done 4s². This trips up almost everyone at first.

2. Thinking Ions Lose Electrons From the Highest Number

Wrong. Positive ions always lose from the outermost s orbital first, then the d. For Fe²⁺, you remove both 4s electrons before touching 3d.

3. Missing the Exceptions

Chromium should be 4s² 3d⁴, but it's actually 4s¹ 3d⁵. Copper should be 4s² 3d⁹, but it's 4s¹ 3d¹⁰. Half-filled and fully-filled subshells are more stable. Memorize these two exceptions and you'll be fine.

4. Writing Noble Gas Notation Incorrectly

[Ar] means everything through argon. [Kr] means everything through krypton. You can only use a noble gas notation if it actually matches the beginning of your configuration. You can't use [Ne] for iron — that's wrong.

Quick Reference: Common Noble Gas Cores

CoreConfigurationUse For
[He]1s²H, Li, Be, B, C, N, O, F, Ne
[Ne]1s² 2s² 2p⁶Na through Ar
[Ar]1s² 2s² 2p⁶ 3s² 3p⁶K through Kr (minus transition metals)
[Kr]Through 4p⁶Elements 37-54 (Rb-Xe)
[Xe]Through 5p⁶Elements 55-86 (Cs-Rn)

How to Practice Effectively

Don't just read these. Write them out by hand.

  1. Pick 10 elements from the list above. Close the answer key.
  2. Write the full configuration from memory. Include every orbital.
  3. Check your answers. Find every mistake and understand why.
  4. Repeat daily until you can do any configuration in under 2 minutes.

That's it. There's no secret method. Repetition fixes this.