Electron Configuration Practice with Answer Key
Electron Configuration Practice: The Only Drill You Need
You need to write electron configurations. You need to verify if you're right. This guide gives you both — 40 practice problems with a complete answer key.
No fluff. No inspirational quotes. Just electrons filling orbitals the way they actually do.
What You Actually Need to Know First
Before you start the problems, make sure these rules are locked in your brain:
- Aufbau Principle: Electrons fill lowest energy orbitals first. The diagram below shows the order.
- Pauli Exclusion Principle: Each orbital holds maximum 2 electrons with opposite spins.
- Hund's Rule: Electrons spread out in degenerate orbitals before pairing up.
The Orbital Filling Order (Memorize This)
Most students draw this as a diagonal diagram. Here's the sequence:
1s → 2s → 2p → 3s → 3p → 4s → 3d → 4p → 5s → 4d → 5p → 6s → 4f → 5d → 6p → 7s → 5f → 6d → 7p
Or easier — fill this pattern diagonally:
1s
2s 2p
3s 3p 4s 3d
4p 5s 4d 5p 6s 4f
5d 6p 7s 5f 6d 7p
Electron Capacity Per Subshell
- s subshell: 2 electrons
- p subshell: 6 electrons
- d subshell: 10 electrons
- f subshell: 14 electrons
Practice Problems
Level 1: Basic Configurations (Problems 1–10)
Write the full electron configuration for each element:
- Hydrogen (H)
- Helium (He)
- Lithium (Li)
- Carbon (C)
- Nitrogen (N)
- Oxygen (O)
- Neon (Ne)
- Sodium (Na)
- Chlorine (Cl)
- Argon (Ar)
Level 2: Transition Metals and Beyond (Problems 11–25)
- Potassium (K)
- Calcium (Ca)
- Iron (Fe)
- Copper (Cu)
- Zinc (Zn)
- Bromine (Br)
- Krypton (Kr)
- Silver (Ag)
- Gold (Au)
- Lead (Pb)
- Mercury (Hg)
- Platinum (Pt)
- Nickel (Ni)
- Manganese (Mn)
- Chromium (Cr)
Level 3: Ions and Exceptions (Problems 26–40)
- Fe²⁺ (Iron ion with 2+ charge)
- Fe³⁺ (Iron ion with 3+ charge)
- Cu⁺ (Copper ion with 1+ charge)
- Cu²⁺ (Copper ion with 2+ charge)
- O²⁻ (Oxide ion)
- Na⁺ (Sodium ion)
- Cl⁻ (Chloride ion)
- S²⁻ (Sulfide ion)
- Ti²⁺ (Titanium ion)
- Ti⁴⁺ (Titanium ion)
- Co²⁺ (Cobalt ion)
- Co³⁺ (Cobalt ion)
- Zn²⁺ (Zinc ion)
- Sn²⁺ (Tin ion)
- Sn⁴⁺ (Tin ion)
Answer Key
Level 1 Answers
| Element | Configuration |
|---|---|
| 1. H | 1s¹ |
| 2. He | 1s² |
| 3. Li | 1s² 2s¹ |
| 4. C | 1s² 2s² 2p² |
| 5. N | 1s² 2s² 2p³ |
| 6. O | 1s² 2s² 2p⁴ |
| 7. Ne | 1s² 2s² 2p⁶ |
| 8. Na | 1s² 2s² 2p⁶ 3s¹ |
| 9. Cl | 1s² 2s² 2p⁶ 3s² 3p⁵ |
| 10. Ar | 1s² 2s² 2p⁶ 3s² 3p⁶ |
Level 2 Answers
| Element | Configuration |
|---|---|
| 11. K | 1s² 2s² 2p⁶ 3s² 3p⁶ 4s¹ |
| 12. Ca | 1s² 2s² 2p⁶ 3s² 3p⁶ 4s² |
| 13. Fe | 1s² 2s² 2p⁶ 3s² 3p⁶ 4s² 3d⁶ |
| 14. Cu | 1s² 2s² 2p⁶ 3s² 3p⁶ 4s¹ 3d¹⁰ |
| 15. Zn | 1s² 2s² 2p⁶ 3s² 3p⁶ 4s² 3d¹⁰ |
| 16. Br | 1s² 2s² 2p⁶ 3s² 3p⁶ 4s² 3d¹⁰ 4p⁵ |
| 17. Kr | 1s² 2s² 2p⁶ 3s² 3p⁶ 4s² 3d¹⁰ 4p⁶ |
| 18. Ag | [Kr] 5s¹ 4d¹⁰ |
| 19. Au | [Xe] 6s¹ 4f¹⁴ 5d¹⁰ |
| 20. Pb | [Xe] 6s² 4f¹⁴ 5d¹⁰ 6p² |
| 21. Hg | [Xe] 6s² 4f¹⁴ 5d¹⁰ |
| 22. Pt | [Xe] 6s¹ 4f¹⁴ 5d⁹ |
| 23. Ni | 1s² 2s² 2p⁶ 3s² 3p⁶ 4s² 3d⁸ |
| 24. Mn | 1s² 2s² 2p⁶ 3s² 3p⁶ 4s² 3d⁵ |
| 25. Cr | 1s² 2s² 2p⁶ 3s² 3p⁶ 4s¹ 3d⁵ |
Level 3 Answers (Ions and Exceptions)
| Ion | Configuration | Notes |
|---|---|---|
| 26. Fe²⁺ | [Ar] 3d⁶ | Lost two 4s electrons |
| 27. Fe³⁺ | [Ar] 3d⁵ | Lost two 4s + one 3d |
| 28. Cu⁺ | [Ar] 3d¹⁰ | 4s electron lost |
| 29. Cu²⁺ | [Ar] 3d⁹ | 4s + one 3d lost |
| 30. O²⁻ | 1s² 2s² 2p⁶ | Same as Ne |
| 31. Na⁺ | 1s² 2s² 2p⁶ | Same as Ne |
| 32. Cl⁻ | 1s² 2s² 2p⁶ 3s² 3p⁶ | Same as Ar |
| 33. S²⁻ | [Ar] | Same as Ar |
| 34. Ti²⁺ | [Ar] 3d² | Lost both 4s electrons |
| 35. Ti⁴⁺ | [Ar] | Lost 4s and 3d² |
| 36. Co²⁺ | [Ar] 3d⁷ | Lost two 4s electrons |
| 37. Co³⁺ | [Ar] 3d⁶ | Lost 4s² + one 3d |
| 38. Zn²⁺ | [Ar] 3d¹⁰ | Lost both 4s electrons |
| 39. Sn²⁺ | [Kr] 5s² 4d¹⁰ 5p² → [Kr] 4d¹⁰ 5p² | Lost both 5s electrons |
| 40. Sn⁴⁺ | [Kr] 4d¹⁰ | Lost 5s² and 5p² |
Where Students Actually Screw Up
1. Forgetting the 4s Fills Before 3d
Calcium is 4s², not 3d². The 3d orbitals don't start filling until after you've done 4s². This trips up almost everyone at first.
2. Thinking Ions Lose Electrons From the Highest Number
Wrong. Positive ions always lose from the outermost s orbital first, then the d. For Fe²⁺, you remove both 4s electrons before touching 3d.
3. Missing the Exceptions
Chromium should be 4s² 3d⁴, but it's actually 4s¹ 3d⁵. Copper should be 4s² 3d⁹, but it's 4s¹ 3d¹⁰. Half-filled and fully-filled subshells are more stable. Memorize these two exceptions and you'll be fine.
4. Writing Noble Gas Notation Incorrectly
[Ar] means everything through argon. [Kr] means everything through krypton. You can only use a noble gas notation if it actually matches the beginning of your configuration. You can't use [Ne] for iron — that's wrong.
Quick Reference: Common Noble Gas Cores
| Core | Configuration | Use For |
|---|---|---|
| [He] | 1s² | H, Li, Be, B, C, N, O, F, Ne |
| [Ne] | 1s² 2s² 2p⁶ | Na through Ar |
| [Ar] | 1s² 2s² 2p⁶ 3s² 3p⁶ | K through Kr (minus transition metals) |
| [Kr] | Through 4p⁶ | Elements 37-54 (Rb-Xe) |
| [Xe] | Through 5p⁶ | Elements 55-86 (Cs-Rn) |
How to Practice Effectively
Don't just read these. Write them out by hand.
- Pick 10 elements from the list above. Close the answer key.
- Write the full configuration from memory. Include every orbital.
- Check your answers. Find every mistake and understand why.
- Repeat daily until you can do any configuration in under 2 minutes.
That's it. There's no secret method. Repetition fixes this.